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ResearcherID: F-2955-2012/
ORCID: 0000-0003-1502-6038

 

Publications

2020

(48) Synergistic Effect of Heterostructured Dissimilar Metal-Organic Framework Thin Films on Adsorption Properties
Z. Wang, S. Wannapaiboon, S. Henke, M. Paulus, K. Rodewald, B. Rieger, R. A. Fischer
J. Mater. Chem. A 2020, DOI: 10.1039/C9TA10264G.

(47) Photochemical Approach to the Cyclohepta[b]indole Scaffold by Annulative Two-Carbon Ring-Expansion
D. C. Tymann, L. Benedix, L. Iovkova, R. Pallach, S. Henke, D. Tymann, M. Hiersemann
Chem. Eur. J. 2020, DOI: 10.1002/chem.202002581.

(46) Defect Creation in Surface Mounted Metal-Organic Framework Thin Films
Z. Wang, S. Henke, M. Paulus, A. Welle, Z. Fan, K. Rodewald, B. Rieger, R. A. Fischer
ACS Appl. Mater. Interfaces 2020, 12, 2655–2661.

2019

(45) Meltable Mixed-Linker Zeolitic Imidazolate Frameworks and Their Microporous Glasses - From Melting Point Engineering to Selective Hydrocarbon Sorption
L. Frentzel-Beyme, M. Kloss, P. Kolodzeiski, R. Pallach, S. Henke*
J. Am. Chem. Soc. 2019, 141, 12362–12371.

(44)  Redetermination of the crystal structure of tetrammineplatinum(II) dichloride - A microporous hydrogen-bonded 3D network exhibiting a temperature-dependent order-disorder phase transition
L. Brieger, S. Henke, A. S. Mohamed, I. Jourdain, M. Knorr, C. Strohmann
Inorg. Chim. Acta 2019, 495, 119002.

(43) Flexibility control in alkyl ether-functionalized pillared-layered MOFs by a Cu/Zn mixed metal approach
A. Schneemann,  R. Rudolf,  S. J. Baxter,  P. Vervoorts,  I. Hante,  K. Khaletskaya,  S. Henke,  G. Kieslich, R. A. Fischer
Dalton Trans. 2019, 48, 6564-6570.

(42) Porous purple glass - A cobalt imidazolate glass with accessible porosity from a meltable cobalt imidazolate framework
L. Frentzel-Beyme, M. Kloß, R. Pallach, S. Salamon, H. Moldenhauer, J. Landers, H. Wende, J. Debus, S. Henke*
J. Mater. Chem. A 2019, 7, 985-990.

(41) Control of Metal–Organic Framework Crystallization by Metastable Intermediate Pre-equilibrium Species
H. H.-M. Yeung, A. F. Sapnik, F. Massingberd-Mundy, M. W. Gaultois, Y. Wu, D. X. Fraser, S. Henke, R. Pallach, N. Heidenreich, O. Magdysyuk, N. T. Vo, A. L. Goodwin
Angew. Chem. Int. Ed. 2019, 58, 566-571.
Angew. Chem. 2019, 131, 576-581.

2018

(40)  Fabrication of Zinc-Dicarboxylate- and Zinc-Pyrazolate-Carboxylate-Framework Thin Films through Vapour-Solid Deposition
R. Medishetty, Z. Zhang, A. Sadlo, S. Cwik, D. Peeters, S. Henke, N. Mangayarkarasi, A. Devi
Dalton Trans. 2018, 47, 14179-14183

(39) Different Breathing Mechanisms in Flexible Pillared-Layered Metal-Organic Frameworks − Impact of the Metal Center
A. Schneemann, P. Vervoorts, I. Hante, M. Tu, S. Wannapaiboon, C. Sternemann, M. Paulus, D. C. F. Wieland, S. Henke*,  R. A. Fischer* 
Chem. Mater. 2018, 30, 1667-1676

(38) Pore closure in zeolitic imidazolate frameworks under mechanical pressure
S. Henke*, M. T. Wharmby, G. Kieslich, I. Hante, A. Schneemann, Y. Wu, D. Daisenberger, A. K. Cheetham
Chem. Sci. 2018, 9, 1654-1660

2017

(37) Multi-Photon Absorption in Metal-Organic Frameworks
R. Medishetty, L. Nemec, V. Nalla, S. Henke, M. Samoc, K. Reuter, R. A. Fischer
Angew. Chem. Int. Ed. 2017, 56, 14743-14748
Angew. Chem. 2017, 129, 14938-14943

(36) Linker Functionalization Triggers an Alternative 3D-Topology for Zn-Isophthalate-4,4’-Bipyridine Frameworks
A. Schneemann, R. Rudolf, S. Henke, Y. Takahashi, H. Banh, I. Hante, C. Schneider, S.-i. Noro, R. A. Fischer
Dalton Trans. 2017, 46, 8198-8203.

(35) A New Class of Lasing Materials: Intrinsic Stimulated Emission from Nonlinear Optically Active Metal–Organic Frameworks
R. Medishetty, V. Nalla, L. Nemec, S. Henke, D. Mayer, H. Sun, K. Reuter, R. A. Fischer
Adv. Mater. 2017, 29, 1605637 (highlighted on the Front Cover)

(34) Functional Conductive Nanomaterials via Polymerisation in Nano-channels: PEDOT in a MOF
T. Wang, M. Farajollahi, S. Henke, T. Zhu, S. R. Bajpe, S. Sun, J. S. Barnard, J. S. Lee, J. Madden, A. K. Cheetham, S. Smoukov
Mater. Horiz. 2017, 4, 64-71 (highlighted on the Front Cover)

2016

(33) Systematic molecular engineering of Zn-ketoiminates for application as precursors in atomic layer depositions of zinc oxide
R. O’Donoghue, D. Peeters, D. Rogalla, H.-W. Becker, J. Rechmann, S. Henke, M. Winter, A. Devi
Dalton Trans. 2016, 45, 19012-19023

(32) Time-Resolved In Situ X-ray Diffraction Reveals Metal-Dependent Metal-Organic Framework Formation
Y. Wu, S. Henke, G. Kieslich, I. Schwedler, M. Yang, D. A. X. Fraser, D. O’Hare
Angew. Chem. Int. Ed. 2016, 55, 14081-14084
Angew. Chem. 2016, 128, 14287-14290

(31) Liquid Exfoliation of Alkyl-Ether-Functionalised Layered Metal-Organic Frameworks to Nanosheets
J. F. Foster, S. Henke, A. Schneemann, R. A. Fischer, A. K. Cheetham
Chem. Commun. 2016, 52, 10474-10477 (highlighted on the Front Cover)

(30) Disorder and Polymorphism in Cu(II)-polyoxometalate complexes: [Cu1.5(H2O)7.5PW12O40]·4.75H2O, cis– & trans-[Cu2(H2O)10SiW12O40]·6H2O”
S. R. Bajpe, S. Henke, J.-H. Lee, P. D. Bristowe, A. K. Cheetham
CrystEngComm 2016, 18, 5327-5332

(29) Transition Metal Coordination Complexes of Chrysazin
P. J. Beldon, S. Henke, B. Monserrat, S. Tominaka, N. Stock, A. K. Cheetham
CrystEngComm 2016, 18, 5121-5129

(28) Tuneable mechanical and dynamical properties in the ferroelectric perovskite solid solution [NH3NH2]1-x[NH3OH]xZn(HCOO)3
G. Kieslich, S. Kumagai, A. C. Forse, S. Sun, S. Henke, M. Yamashita, C. P. Grey, A. K. Cheetham
Chem. Sci. 2016, 7, 5108–5112

(27) In Situ Observation of Successive Crystallizations and Metastable Intermediates in the Formation of Metal–Organic Frameworks
H. H.-M. Yeung, Y. Wu, S. Henke, A. K. Cheetham, D. O’Hare, R. I. Walton
Angew. Chem. Int. Ed. 2016, 55, 2012–2016
Angew. Chem. 2016, 128, 2052–2056

(26) Mixed-Linker Solid Solutions of Functionalized Pillared-Layer MOFs – Adjusting Structural Flexibility, Gas Sorption, and Thermal Responsiveness
I. Schwedler, S. Henke*, M. T. Wharmby, S. R. Bajpe, A. K. Cheetham*, R. A. Fischer*
Dalton Trans. 2016, 45, 4230-4241 (HOT Article; highlighted on the Inside Front Cover of the themed issue on “Flexibility and Disorder in Metal-Organic Frameworks“)

(25) Coordination environments and π-conjugation in dense lithium coordination polymers
S. Tominaka, H. H.-M. Yeung, S. Henke, A. K. Cheetham
CrystEngComm 2016, 18, 398–406 (highlighted on the Front Cover)

2015

(24) Mechanical Properties of a Calcium Dietary Supplement, Calcium Fumarate Trihydrate
S. Sun, S. Henke, M. T. Wharmby, H. H.-M. Yeung, W. Li, A. K. Cheetham
Inorg. Chem. 2015, 54, 11186–11192

(23) Influence of Solvent-Like Sidechains on the Adsorption of Light Hydrocarbons in Metal–Organic Frameworks
A. Schneemann, E. D. Bloch, S. Henke, P. Llewellyn, J. R. Long, R. A. Fischer
Chem. Eur. J. 2015, 21, 18764–18769

(22) Hybrid glasses from strong and fragile metal-organic framework liquids
T. D. Bennett, J.-C. Tan, Y. Yue, E. Baxter, C. Ducati, N. J. Terrill, H. H.-M Yeung, Z. Zhou, W. Chen, S. Henke, A. K. Cheetham, G. N. Greaves
Nat. Commun. 2015, 6, 8079

(21) Structural flexibility in prototypical zeolitic imidazolate frameworks
M. T. Wharmby, S. Henke, T. D. Bennett, C. Mellot-Draznieks, Y. Yue, A. K. Cheetham
Acta Cryst. 2015, A71, s85-s86

(20) Extreme Flexibility in a Zeolitic Imidazolate Framework: Porous to Dense Phase Transition in Desolvated ZIF-4
M. T. Wharmby, S. Henke, T. D. Bennett, S. R. Bajpe, I. Schwedler, S. P. Thompson, F. Gozzo, P. Simoncic, C. Mellot-Draznieks, H. Tao, Y. Yue, A. K. Cheetham
Angew. Chem. Int. Ed. 2015, 54, 6447–6451
Angew. Chem. 2015, 127, 6547–6551

(19) Manganese Tetraboride, MnB4: High-Temperature Crystal Structure, p–n Transition, 55Mn NMR Spectroscopy, Solid Solutions, and Mechanical Properties
A. Knappschneider, C. Litterscheid, J. Brgoch, N. C. George, S. Henke, A. K. Cheetham, J. G. Hu, R. Seshadri, B. Albert
Chem. Eur. J. 2015, 21, 8177–8181

(18) Characteristics of flexibility in metal-organic framework solid solutions of composition [Zn2(BME-bdc)x(DB-bdc)2-xdabco]n: In situ powder X-ray diffraction, in situ NMR spectroscopy, and molecular dynamics simulations
V. Bon, J. Pallmann, E. Eisbein, H. C. Hoffmann, I. Senkovska, I. Schwedler, A. Schneemann, S. Henke, D. Wallacher, R. A. Fischer, G. Seifert, E. Brunner, S. Kaskel
Microporous Mesoporous Mater. 2015, 216, 64–74

2014

(17)  Mechanical Properties of Metal-Organic Frameworks – Influence of Structure and Chemical Bonding
W. Li*, S. Henke*, A. K. Cheetham
APL Mater. 2014, 2, 123902 (invited Research Update)

(16)  Identifying the Role of Terahertz Vibrations in Metal-Organic Frameworks: From Gate-Opening Phenomenon to Shear-Driven Structural Destabilization
M. R. Ryder, B. Civalleri, T. D. Bennett, S. Henke, S. Rudic, G. Cinque, F. Fernandez-Alonso, J.-C. Tan
Phys. Rev. Lett. 2014, 113, 215502

(15) Perfect and Stable Hybrid Glasses from Strong and Fragile Metal-Organic Framework Liquids
T. D. Bennett, J. C. Tan, Y. Z. Yue, C. Ducati, N. Terril, H. H.-M. Yeung, Z. Zhou, W. Chen, S. Henke, A. K. Cheetham, G. N. Greaves
2014, arXiv:1409.3980

(14) Mechanical Tunability via Hydrogen Bonding in Metal-Organic Frameworks with the Perovskite Architecture
W. Li, T. Alagarsamy, P. T. Barton, Z. Lin, S. Henke, H. H.-M. Yeung, M. T. Wharmby, Erica G. Bithell, C. J. Howard, A. K. Cheetham
J. Am. Chem. Soc. 2014, 136, 7801–7804

(13) Guest-Dependent Mechanical Anisotropy in Pillared-Layered Soft Porous Crystals – A Nanoindentation Study
S. Henke*, W. Li, A. K. Cheetham*
Chem. Sci. 2014, 5, 2392–2397

(12) Targeted Manipulation of Metal-Organic Frameworks To Direct Sorption Properties
A. Schneemann, S. Henke, I. Schwedler, R. A. Fischer
ChemPhysChem 2014, 15, 823–839 (Minireview)

2013

(11) Massive Anisotropic Thermal Expansion and Thermo-Responsive Breathing in Metal-Organic Frameworks Modulated by Linker Functionalization
S. Henke*, A. Schneemann, R. A. Fischer*
Adv. Funct. Mater. 2013, 23, 5990-5996 (highlighted on the Inside Front Cover)

(10) Coordination polymers of alkali metal trithiocyanurates: structure determinations and ionic conductivity measurements using single crystals
S. Tominaka, S. Henke, A. K. Cheetham
CrystEngComm 2013, 15, 9400–9407 (highlighted on the Inside Front Cover)

2012

(9) Directing the Breathing-Behavior of Pillared-Layered Metal-Organic Frameworks via a Systematic Library of Functionalized Linkers Bearing Flexible Substituents
S. Henke, A. Schneemann, A. Wütscher, R. A. Fischer
J. Am. Chem. Soc. 2012, 134, 9464–9474

(8) Zinc-1,4-Benzene-dicarboxylate-Bipyridine Frameworks – Linker Functionalization Impacts Network Topology During Solvothermal Synthesis
S. Henke, A. Schneemann, S. Kapoor, R. Winter, R. A. Fischer
J. Mater. Chem. 2012, 22, 909–918

(7) Fabrication of a CO2-selective membrane by stepwise liquid-phase deposition of an alkyl ether functionalized pillared-layered metal-organic framework [Cu2L2P]n on a macroporous support
A. Bétard, H. Bux, S. Henke, D. Zacher, J. Caro, R. A. Fischer
Microporous Mesoporous Mater. 2012, 150, 76–82

2011

(6) Multiple Phase-Transitions upon Selective CO2 Adsorption in an Alkyl Ether Functionalized Metal-Organic Framework – An In Situ X-ray Diffraction Study
S. Henke, D. C. F. Wieland, M. Meilikhov, M. Paulus, C. Sternemann, K. Yusenko, R. A. Fischer
CrystEngComm 2011, 13, 6399–6404 (selected as Hot Article)

(5) Gated Channels in a Honeycomb-like Zinc-Dicarboxylate-Bipyridine Framework with Flexible Alkyl Ether Side Chains
S. Henke, R. A. Fischer
J. Am. Chem. Soc. 2011, 133, 2064–2067 (highlighted at CGDnetwork: Structure of the Week #18)

(4) Liquid-Phase Epitaxy of Multicomponent Layer-Based Porous Coordination Polymer Thin Films of [M(L)(P)0.5] Type: Importance of Deposition Sequence on the Oriented Growth
D. Zacher, K. Yusenko, A. Bétard, S. Henke, M. Molon, T. Ladnorg, O. Shekhah, B. Schüpbach, T. de los Arcos, M. Krasnopolski, M. Meilikhov, J. Winter, A. Terfort, C. Wöll, R. A. Fischer
Chem. Eur. J. 2011, 17, 1448–1455 (highlighted with a Frontispiece)

2010

(3) Flexibility and Sorption Selectivity in Rigid Metal-Organic Frameworks: The Impact of Ether-Functionalised Linkers
S. Henke, R. Schmid, J.-D. Grunwaldt, R. A. Fischer
Chem. Eur. J. 2010, 16, 14296–14306 (highlighted with a Frontispiece)

(2) Atmend und Multivariant
S. Henke, R. A. Fischer
Nachr. Chem. 2010, 58, 634–639 (German review article)

2009

(1) Simultaneous Gas-Phase Loading of MOF-5 with Two Metal Precursors: towards Bimetallics@MOF
F. Schröder, S. Henke, X. Zhang, R. A. Fischer
Eur. J. Inorg. Chem. 2009, 3131–3140

Location & approach

The campus of TU Dort­mund University is located close to interstate junction Dort­mund West, where the Sauerlandlinie A 45 (Frankfurt-Dort­mund) crosses the Ruhrschnellweg B 1 / A 40. The best interstate exit to take from A 45 is "Dort­mund-Eichlinghofen" (closer to Campus Süd), and from B 1 / A 40 "Dort­mund-Dorstfeld" (closer to Campus Nord). Signs for the uni­ver­si­ty are located at both exits. Also, there is a new exit before you pass over the B 1-bridge leading into Dort­mund.

To get from Campus Nord to Campus Süd by car, there is the connection via Vogelpothsweg/Baroper Straße. We recommend you leave your car on one of the parking lots at Campus Nord and use the H-Bahn (suspended monorail system), which conveniently connects the two campuses.

TU Dort­mund University has its own train station ("Dort­mund Uni­ver­si­tät"). From there, suburban trains (S-Bahn) leave for Dort­mund main station ("Dort­mund Hauptbahnhof") and Düsseldorf main station via the "Düsseldorf Airport Train Station" (take S-Bahn number 1, which leaves every 20 or 30 minutes). The uni­ver­si­ty is easily reached from Bochum, Essen, Mülheim an der Ruhr and Duisburg.

You can also take the bus or subway train from Dort­mund city to the uni­ver­si­ty: From Dort­mund main station, you can take any train bound for the Station "Stadtgarten", usually lines U41, U45, U 47 and U49. At "Stadtgarten" you switch trains and get on line U42 towards "Hombruch". Look out for the Station "An der Palmweide". From the bus stop just across the road, busses bound for TU Dort­mund University leave every ten minutes (445, 447 and 462). Another option is to take the subway routes U41, U45, U47 and U49 from Dort­mund main station to the stop "Dort­mund Kampstraße". From there, take U43 or U44 to the stop "Dort­mund Wittener Straße". Switch to bus line 447 and get off at "Dort­mund Uni­ver­si­tät S".

The H-Bahn is one of the hallmarks of TU Dort­mund University. There are two stations on Campus Nord. One ("Dort­mund Uni­ver­si­tät S") is directly located at the suburban train stop, which connects the uni­ver­si­ty directly with the city of Dort­mund and the rest of the Ruhr Area. Also from this station, there are connections to the "Technologiepark" and (via Campus Süd) Eichlinghofen. The other station is located at the dining hall at Campus Nord and offers a direct connection to Campus Süd every five minutes.

The AirportExpress is a fast and convenient means of transport from Dort­mund Airport (DTM) to Dort­mund Central Station, taking you there in little more than 20 minutes. From Dort­mund Central Station, you can continue to the uni­ver­si­ty campus by interurban railway (S-Bahn). A larger range of in­ter­na­tio­nal flight connections is offered at Düsseldorf Airport (DUS), which is about 60 kilometres away and can be directly reached by S-Bahn from the uni­ver­si­ty station.

The facilities of TU Dort­mund University are spread over two campuses, the larger Campus North and the smaller Campus South. Additionally, some areas of the uni­ver­si­ty are located in the adjacent "Technologiepark".

Site Map of TU Dort­mund University (Second Page in English).