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selected articles and letters

Cyclopentanoids by Uncatalyzed Intramolecular Carbonyl Ene (ICE) Reactions of α-Keto Esters
D. Tymann,* A. Klüppel, W. Hiller, M. Hiersemann* Org. Lett. 2014, 16, accepted

Caztalytic Asymmetric Claisen Rearrangement of Gosteli-Type Allyl Vinyl Ethers: Total Synthesis of (-) -9,10-Dihydro Ecklonialacetone B
J. Becker, L. Butt, V. von Kiedrowski, E. Mischler, F. Quentin, M. Hiersemann* J. Org. Chem. 2014, 79,  3040-3051

Total Synthesis  of (-) -Ecklonialacetone B
J. Becker, L. Butt, V. von Kiedrowski, E. Mischler, F. Quentin, M. Hiersemann* J. Org. Lett. 2013, 5982-5985

"{1,6}-Transannular Catalytic Asymmetric Gosteli–Claisen Rearrangement"
T. Jaschinski, M. Hiersemann* Org. Lett. 2012, 14, 4114–4117 (link)

"Palladium(II)-Catalyzed Cyclosiomerization of Substituted 1,5-Hexadienes: A Combined Experimental and Computational Study on an Open and an Interrupted Hydropalladation/Carbopalladation/β-Hydride Elimination (HCHe) Catalytic Cycle"
B. Nelson*, S. Herres-Pawlis, W. Hiller, H. Preut, C. Strohmann, M. Hiersemann* J. Org. Chem. 2012, 77, 4980–4995 (link)

"Integration of Catalysis and Analysis is the Key: Rapid and Precise Investigation of the Catalytic Asymmetric Gosteli–Claisen Rearrangement"
J. Troendlin, J. Rehbein, M. Hiersemann, O. TrappJ. Am. Chem. Soc. 2011, 133, 16444–16450 (link)

"Palladium(II)-Catalyzed Cycloisomerization of Functionalized 1,5-Hexadienes"
B. Nelson , W. Hiller, A. Pollex, M. Hiersemann* Org. Lett. 2011, 13, 4438–4441 (link)

"Gosteli–Claisen Rearrangement of Propargyl Vinyl Ethers: Cascading Molecular Rearrangements"
A. Gille, J. Rehbein, M. Hiersemann* Org. Lett. 2011, 13, 2122–2125 (link)

"Total Synthesis of Natural and Non-Natural Jatrophane Diterpenes and their Evaluation as MDR Modulators"
C. Schnabel, K. Sterz, H. Müller, J. Rehbein, M. Wiese*, M. Hiersemann*J. Org. Chem. 2011, 76,  512–522 (link)

"(–)-Lytophilippine A: Synthesis of a C1–C<18 Building Block"
A. Gille*, M. Hiersemann* Org. Lett2010, 12, 5258–5261 (link)

"Total Synthesis of Jatrophane Diterpenes from Euphorbia characias"
C. Schnabel, M. Hiersemann* Org. Lett., 200911, 2555–2558 (link)

"Gosteli–Claisen Rearrangement: DFT Study of Substituent Rate Effects"
J. Rehbein, M. Hiersemann* J. Org. Chem. 2009, 74, 4336–4342 (link)

"Synthetic Studies toward Jatrophane Diterpenes from Euphorbia characias. Enantioselective Synthesis of(–)-15-O-Acetyl-3-O-propionyl-17-norcharaciol"
H. Helmboldt, M. Hiersemann* J. Org. Chem., 2009, 74, 1698–1708 (link)

"Gosteli–Claisen Rearrangement: Substrate Synthesis, Simple Diastereoselectivity and Kinetic Studies"
J. Rehbein*, S. Leick, M. Hiersemann* J. Org. Chem. 2009, 74, 1531–1540 (link)

"Enantioselective Total Synthesis of the C8-C20 Segment of Curvicollide C"
M. Körner, M. Hiersemann* Org. Lett. 2007, 9, 4979–498 2 (link)

quot; Organocatalytic Claisen Rearrangement: Theory and Experiment"
M. Kirsten, J. Rehbein T. Strassner*, M. Hiersemann* J. Org. Chem. 2007, 72, 4001–4011 (link)

Synthesis of the Norjatrophane Diterpene (–)-15-Acetyl-3-propionyl- 17-norcharaciol
H. Helmboldt, D. Köhler, M. Hiersemann* Org. Lett. 2006, 8, 1573–1576 (link)

"Catalytic Asymmetric Claisen Rearrangement in Natural Product Synthesis: Synthetic Studies toward (–)-Xeniolide F"
A. Pollex, M. Hiersemann* Org. Lett. 2005, 7, 5705–5708 (link)

"Ester Dienolate [2,3]-Wittig Rearrangement in Natural Product Synthesis: Diastereoselective Total Synthesis of the Triester of Viridiofungin A, A2, and A4"
A. Pollex, A. Millet, J. Müller, M. Hiersemann*, L. Abraham J. Org. Chem. 2005, 70, 5579–5591 (link)

"The Cu(OTf)2- and Yb(OTf)3-Catalyzed Claisen Rearrangement of 2-Alkoxycarbonyl-Substituted Allyl Vinyl Ethers"
M. Hiersemann*, L. Abraham Org. Lett. 2001, 3, 49–52 (link)

"Chiral Acetals as Stereoinductors: Diastereoface Selective Alkylation of Dihydrobenzoxazine-Derived Amide Enolates"
J. Mulzer*, O. Langer, M. Hiersemann*, J. W. Bats, J. Buschmann, P. Luger J. Org. Chem. 2000, 65, 6540–6546 (link)