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Anna Krupp

Technische Universität Dortmund
Fakultät für Chemie und Chemische Biologie
Anorganische Chemie
Otto-Hahn-Straße 6
44227 Dortmund

Room: C2-05-328

E-Mail: anna.krupptu-dortmundde
Phone: +49 231 755 3833
Fax: +49 231 755 3797


Portrait Anna Krupp © AK-Strohmann​/​TU Dortmund


Synthesis and transformation of silicon and germanium stereogenic compounds - the stereochemical course of nucleophilic substitutions on Si-/Ge-stereogenic compounds is in particular focus. Such stereogenic systems are meant to be built up as atom-economically as possible via asymmetric syntheses and to allow the intensive investigation of the stereochemical course of the substitution of the remaining functional groups in direct connection. A combination of single crystal X-ray structural analysis, GC/EI-MS and NMR will be used to elucidate the absolute configurations. By combining the experimental observations with quantum chemical calculations, we also aim to establish mechanism hypotheses.